The National Enquirer suggested that the Oscar nominated pair had shaken on a deal that George would take care of Brangelina's brood if he lost out to him in the Best Actor category.
But speaking exclusively to omg! tonight on the red carpet at the BAFTAs, the Descendants star said: "That's a made up story. I hate to disappoint you."
Asked whether he'd like to look after Brad's children, George looked pretty horrified and said: "No we never had that conversation."
Err. So that's a no then George.
Whilst most of the stars on the red carpet in London were shivering in the cold, the Hollywood star told us he was coping well with the British weather.
He said: "It's not so cold if you're wearing an overcoat. See that girl down there with no sleeves on."
Not if you're hot like you George. Not if you're hot like you.